Chemiluminescence of CdTe nanocrystals induced by direct chemical oxidation and its size-dependent and surfactant-sensitized effect.

作者: Zhouping Wang , Jun Li , Bin Liu , Jianqiang Hu , Xin Yao

DOI: 10.1021/JP055023K

关键词: ChemiluminescenceAqueous solutionNanostructureHydrogen peroxidePhotoluminescenceThioglycolic acidPulmonary surfactantChemistryPhotochemistryPotassium permanganate

摘要: CdTe nanocrystals (NCs) capped with thioglycolic acid (TGA) were synthesized via a microwave-assisted method. The chemiluminescence (CL) of NCs induced by directly chemical oxidation and its size-depended surfactant-sensitized effect in aqueous solution then investigated. It was found that oxidants, especially hydrogen peroxide potassium permanganate, could oxidize to produce strong CL emission basic conditions. oxidized displayed size-dependent intensity increased along increasing the sizes NCs. Moreover, could, if surfactants CTAB or β-cyclodextrin added above system, be sensitized some degree. is mainly contributing formation aggregate nanostructure micellar micronanoenvironment, respectively. possible mechanisms further examined means photoluminescence spectra, transmissi...

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