Size dependence of the kinetic rate constant for phase transformation in TiO2 nanoparticles

作者: Hengzhong Zhang , Jillian F. Banfield

DOI: 10.1021/CM0508423

关键词: ChemistryThermodynamicsTio2 nanoparticlesExponential functionSize dependenceArrhenius equationEntropy of activationPhase (matter)Transformation (function)Kinetic rate constant

摘要: … size is another factor that is needed in the description of kinetics of phase transformations in nanoparticles. … sizes of the two samples are different, their rate constants (kN 0 ) should be …

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