Systematics of salt precipitation in complexes of polyethylene oxide and alkali metal iodides

作者: J. Bastek , N.A. Stolwijk , Th. K.-J. Köster , L. van Wüllen

DOI: 10.1016/J.ELECTACTA.2009.04.040

关键词: Ionic bondingPrecipitation (chemistry)Ionic conductivityInorganic chemistryThermal analysisConductivityDifferential scanning calorimetryAlkali metalAtmospheric temperature rangeChemistry

摘要: … Complexes of poly(ethylene oxide) (PEO) or poly(propylene oxide) (PPO) with alkali metal … The present work deals with PEO complexed with different alkali metal iodides. SP in these …

参考文章(22)
J. R. MacCallum, Colin Angus Vincent, Polymer electrolyte reviews Elsevier Applied Science. ,(1987)
John Crank, The mathematics of diffusion ,(1956)
Helmut Mehrer, Diffusion in solids ,(2007)
C.K Chiang, G.T Davis, C.A Harding, J Aarons, Preparation and properties of polymeric solid electrolyte: Polyethylene oxide--sodium iodide complexes Solid State Ionics. pp. 1121- 1123 ,(1983) , 10.1016/0167-2738(83)90140-6
J. J. Fontanella, M. C. Wintersgill, M. K. Smith, J. Semancik, C. G. Andeen, Effect of high pressure on electrical relaxation in poly(propylene oxide) and electrical conductivity in poly(propylene oxide) complexed with lithium salts Journal of Applied Physics. ,vol. 60, pp. 2665- 2671 ,(1986) , 10.1063/1.337093
S. G. Greenbaum, Y. S. Pak, M. C. Wintersgill, J. J. Fontanella, J. W. Schultz, C. G. Andeen, NMR, DSC, DMA, and High Pressure Electrical Conductivity Studies in PPO Complexed with Sodium Perchlorate Journal of The Electrochemical Society. ,vol. 135, pp. 235- 238 ,(1988) , 10.1149/1.2095562
S OBEIDI, B ZAZOUM, N STOLWIJK, Ionic tracer diffusion and dc conductivity in the polymer electrolyte PEO30NaI Solid State Ionics. ,vol. 173, pp. 77- 82 ,(2004) , 10.1016/J.SSI.2004.07.055
N. A. Stolwijk, M. Wiencierz, Sh. Obeidi, Mass and charge transport in the PEO–NaI polymer electrolyte system: effects of temperature and salt concentration Faraday Discussions. ,vol. 134, pp. 157- 169 ,(2007) , 10.1039/B602143N