g-C3N4-Based Nanomaterials for Visible Light-Driven Photocatalysis

作者: Santosh Kumar , Sekar Karthikeyan , Adam Lee

DOI: 10.3390/CATAL8020074

关键词: Water splittingNanotechnologyComposite numberQuantum efficiencyDegradation (geology)PhotocatalysisNanomaterialsMaterials scienceGraphitic carbon nitrideSemiconductor

摘要: Graphitic carbon nitride (g-C3N4) is a promising material for photocatalytic applications such as solar fuels production through CO2 reduction and water splitting, environmental remediation the degradation of organic pollutants. This promise reflects advantageous photophysical properties g-C3N4 nanostructures, notably high surface area, quantum efficiency, interfacial charge separation transport, ease modification either composite formation or incorporation desirable functionalities. Here, we review recent progress in synthesis diverse nanostructured materials, highlight physical basis underpinning their performance each application. Potential new architectures, hierarchical that may offer further enhancements energy harvesting conversion are also outlined.

参考文章(286)
Masakazu. Anpo, Takahito. Shima, Sukeya. Kodama, Yutaka. Kubokawa, Photocatalytic hydrogenation of propyne with water on small-particle titania: size quantization effects and reaction intermediates The Journal of Physical Chemistry. ,vol. 91, pp. 4305- 4310 ,(1987) , 10.1021/J100300A021
Jiali Lv, Kai Dai, Jinfeng Zhang, Lei Geng, Changhao Liang, Qiangchun Liu, Guangping Zhu, Chen Chen, Facile synthesis of Z-scheme graphitic-C3N4/Bi2MoO6 nanocomposite for enhanced visible photocatalytic properties Applied Surface Science. ,vol. 358, pp. 377- 384 ,(2015) , 10.1016/J.APSUSC.2015.06.183
Thomas Faunce, Stenbjorn Styring, Michael R. Wasielewski, Gary W. Brudvig, A. William Rutherford, Johannes Messinger, Adam F. Lee, Craig L. Hill, Huub deGroot, Marc Fontecave, Doug R. MacFarlane, Ben Hankamer, Daniel G. Nocera, David M. Tiede, Holger Dau, Warwick Hillier, Lianzhou Wang, Rose Amal, Artificial photosynthesis as a frontier technology for energy sustainability Energy and Environmental Science. ,vol. 6, pp. 1074- 1076 ,(2013) , 10.1039/C3EE40534F
Santosh Kumar, Arabinda Baruah, Surendar Tonda, Bharat Kumar, Vishnu Shanker, B. Sreedhar, Cost-effective and eco-friendly synthesis of novel and stable N-doped ZnO/g-C3N4 core–shell nanoplates with excellent visible-light responsive photocatalysis Nanoscale. ,vol. 6, pp. 4830- 4842 ,(2014) , 10.1039/C3NR05271K
Bo Weng, Siqi Liu, Zi-Rong Tang, Yi-Jun Xu, One-dimensional nanostructure based materials for versatile photocatalytic applications RSC Advances. ,vol. 4, pp. 12685- 12700 ,(2014) , 10.1039/C3RA47910B
Po Wu, Jiarui Wang, Jing Zhao, Liejin Guo, Frank E. Osterloh, High alkalinity boosts visible light driven H2 evolution activity of g-C3N4 in aqueous methanol Chemical Communications. ,vol. 50, pp. 15521- 15524 ,(2014) , 10.1039/C4CC08063G
Jian Tian, Zhenhuan Zhao, Anil Kumar, Robert I. Boughton, Hong Liu, Recent progress in design, synthesis, and applications of one-dimensional TiO2 nanostructured surface heterostructures: a review Chemical Society Reviews. ,vol. 43, pp. 6920- 6937 ,(2014) , 10.1039/C4CS00180J
A FUJISHIMA, X ZHANG, D TRYK, TiO2 photocatalysis and related surface phenomena Surface Science Reports. ,vol. 63, pp. 515- 582 ,(2008) , 10.1016/J.SURFREP.2008.10.001
Jianhua Sun, Jinshui Zhang, Mingwen Zhang, Markus Antonietti, Xianzhi Fu, Xinchen Wang, Bioinspired hollow semiconductor nanospheres as photosynthetic nanoparticles Nature Communications. ,vol. 3, pp. 1139- ,(2012) , 10.1038/NCOMMS2152