The infrared and Raman spectra of cyclohexane and cyclohexane-d12
作者： Foil A. Miller , Helen R. Golob
DOI: 10.1016/0371-1951(64)80133-8
关键词: Infrared 、 Physical chemistry 、 Chemistry 、 Molecule 、 Deuterium 、 Analytical chemistry 、 Methylene 、 Cyclohexane 、 Raman spectroscopy 、 General Earth and Planetary Sciences 、 General Environmental Science
摘要: Abstract This paper, reports the infrared spectrum of cyclohexane (100–3400 cm−1) and cyclohexane-d12 (300–3400 cm−1), Raman with polarizations for both compounds. With these data vibrational assignments have been advanced considerably. Suggestions made all but two spectroscopically-active fundamentals, four totally-inactive frequencies are still unknown. The deuterated molecule required extensive modifications in previous assignments. One puzzling feature is rather strong evidence a methylene rocking frequency at 384 cm−1 cyclohexane, which startlingly low.
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