Process for preparing fluorine-containing polymers

作者: James T Hill , Michael E Garabedian

DOI:

关键词: Polymer chemistryHexafluoropropylenePolymerizationHexafluoropropylene oxideFluorinePolymerEthylene glycolMaterials scienceSolventCatalysis

摘要: A PROCESS HAVING BENEFICIAL UTILITY IN THE MANUFACTURE OF FLUORINE-CONTAINING POLYMERS FROM HFPO (HEXAFLUOROPROPYLENE OXIDE), ESPECIALLY USEFUL FOR APPLICATIONS REQUIRING DIFUNCTIONAL POLYMER PRODUCTS THAT ARE SUBSTANTIALLY FREE MONOFUNCTIONAL POLYMER. POLYMERIZATION EMPLOYS MIXTURE AND CATALYST; CATALYST, WHICH PREFERABLY CESIUM FLUORIDE, IS MADE UP SOLUTION AN ETHYLENE GLYCOL ETHER PARTICULAR ORGANIC COMPOUND CONTAINING BOTH FLUORINE. REACTION ZONE AT ABOUT -30 TO -60* C., IT CONTAINS HEXAFLUOROPROPYLENE OR LIKE AS SOLVENT

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