作者: James T Hill , Michael E Garabedian
DOI:
关键词: Polymer chemistry 、 Hexafluoropropylene 、 Polymerization 、 Hexafluoropropylene oxide 、 Fluorine 、 Polymer 、 Ethylene glycol 、 Materials science 、 Solvent 、 Catalysis
摘要: A PROCESS HAVING BENEFICIAL UTILITY IN THE MANUFACTURE OF FLUORINE-CONTAINING POLYMERS FROM HFPO (HEXAFLUOROPROPYLENE OXIDE), ESPECIALLY USEFUL FOR APPLICATIONS REQUIRING DIFUNCTIONAL POLYMER PRODUCTS THAT ARE SUBSTANTIALLY FREE MONOFUNCTIONAL POLYMER. POLYMERIZATION EMPLOYS MIXTURE AND CATALYST; CATALYST, WHICH PREFERABLY CESIUM FLUORIDE, IS MADE UP SOLUTION AN ETHYLENE GLYCOL ETHER PARTICULAR ORGANIC COMPOUND CONTAINING BOTH FLUORINE. REACTION ZONE AT ABOUT -30 TO -60* C., IT CONTAINS HEXAFLUOROPROPYLENE OR LIKE AS SOLVENT