Redox chemistry and functionalities of conjugated ferrocene systems
作者： Hiroshi Nishihara
DOI: 10.1016/S0898-8838(02)53003-8
关键词: Combinatorial chemistry 、 Redox 、 Electron transfer 、 Isomerization 、 Intramolecular force 、 Ferrocene 、 Conjugated system 、 Primary (chemistry) 、 Chemistry
摘要: Publisher Summary This chapter provides an overview of reports concerning conjugated ferrocene systems in the following three categories: (1) oligo- .and poly-ferrocenylenes, (2) oligomers and polymers with spacers, (3) ferrocene–acceptor compounds. The reviews studies mixed-valence complexes; as a result, redox properties functionalities are primary focus. In particular, analysis intramolecular electronic interaction based on neighboring-site model, isomerization behavior azoferrocene, proton-coupled electron transfer ferrocene–quinone complexes described each category. fundamental properties, especially behavior, have been surveyed. Various kinds dinuclear synthesized their physical investigated. To understand electron-transfer mechanism dynamics such is important elucidating concepts regarding development redox-based molecular devices. next stage research should be to identify events between multiple nuclei, control internuclear using external stimuli, combine abilities ferrocene.
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