Synthesis and properties of chiral molecular clefts related to Troeger's base
作者： JENNIFER J. TURNER , MARGARET M. HARDING
DOI: 10.1080/10610270500073796
关键词: Supramolecular chemistry 、 Nonane 、 Chemistry 、 Stereochemistry 、 Tröger's base 、 Bicyclic molecule 、 Molecular recognition 、 Troeger's base
摘要: The chiral cavities present in 2,3:6,7-dibenzo-9-oxabicyclonona-2,6-diene, dibenzobicyclo[b,f][3.3.1]nona-5a, 6a-diene-6,12-dione, bicyclo[3.3.1]nonane and dibenzobicyclo[b,f][1,5]diazocines are reminiscent of Troger's base, which has been widely used as a molecular cleft supramolecular chemistry. synthetic methodology to provide key derivatives for elaboration into new structures, efficient resolution methods, the introduction additional recognition groups applications chemistry these structurally related clefts reviewed.
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