Facile Palladium catalyzed decarboxylative allylation of active methylene compounds under neutral conditions using allylic carbonates
作者： Jiro Tsuji , Isao Shimizu , Ichiro Minami , Yukihiro Ohashi
DOI: 10.1016/S0040-4039(00)85719-6
关键词: Catalysis 、 Organic chemistry 、 Allylic rearrangement 、 Methylene 、 Chemistry 、 Palladium
摘要: Abstract Palladium catalyzed decarboxylative allylation of active methylene compounds proceeded under mild neutral conditions using allylic carbonates, which are much more reactive than acetates or phenoxides used commonly in the reaction.
elsevier.com
sci-hub.se 参考文章(7)
Jiro Tsuji, Hideaki Kataoka, Yuichi Kobayashi, Regioselective 1,4-addition of nucleophiles to 1,3-diene monoepoxides catalyzed by palladium complex Tetrahedron Letters. ,vol. 22, pp. 2575- 2578 ,(1981) , 10.1016/S0040-4039(01)90524-6
F. Guibe, Y.Saint M'leux, The allyloxycarbonyl group for alcohol protection: quantitative removal or transformation into allyl protecting group via π-allyl complexes of palladium Tetrahedron Letters. ,vol. 22, pp. 3591- 3594 ,(1981) , 10.1016/S0040-4039(01)81967-5
Barry M. Trost, Gary A. Molander, Neutral alkylations via palladium(0) catalysis Journal of the American Chemical Society. ,vol. 103, pp. 5969- 5972 ,(1981) , 10.1021/JA00409A082
Keiji Yamamoto, Jiro Tsuji, PALLADIUM-CATALYZED ASYMMETRIC CYCLIZATION OF METHYL (E)-OXO-9-PHENOXY-7-NONENOATE AND ITS ANALOGS Tetrahedron Letters. ,vol. 23, pp. 3089- 3092 ,(1982) , 10.1016/S0040-4039(00)87540-1
Barry M. Trost, Organopalladium intermediates in organic synthesis Tetrahedron. ,vol. 33, pp. 2615- 2649 ,(1977) , 10.1016/0040-4020(77)80284-6
Barry M. Trost, New rules of selectivity: allylic alkylations catalyzed by palladium Accounts of Chemical Research. ,vol. 12, pp. 385- 393 ,(1980) , 10.1021/AR50155A001
Jiro Tsuji, Yuichi Kobayashi, Hideaki Kataoka, Takashi Takahashi, New bis- and tris-annulation reagents for the syntheses of CD rings of steroids, bearing a functionalized 18-methyl group, by the palladium-catalyzed cyclization Tetrahedron Letters. ,vol. 21, pp. 3393- 3394 ,(1980) , 10.1016/S0040-4039(00)78697-7