Quadrupole Transitions in CF3Br Investigated by Two-Dimensional Fourier Transform Spectroscopy in the Microwave-Radiofrequency Range

作者: H. Harder , H.W. Nicolaisen , H. Dreizler , H. Mader

DOI: 10.1006/JMSP.1993.1171

关键词: IsotopomersCoupling constantRange (particle radiation)MicrowaveMaterials scienceRotational spectroscopyQuadrupoleAtomic physicsNuclear magnetic resonanceFourier transform spectroscopy

摘要: Abstract "Pure" quadrupole transitions have been observed in CF 3 79 Br and 81 using the technique of two-dimensional Fourier transform spectroscopy microwave radiofrequency range. We for J = 4, 5, 6 K 1, . , 5 ground vibrational state both isotopomers determined coupling Constant eQq 0 its rotational dependencies χ d spin-rotation constants C N For dependence has also determined.

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