4+1 Complexes of zinc phthalocyanine with pyridine derivative ligands
作者： Bartosz Przybył , Jan Janczak
DOI: 10.1016/J.DYEPIG.2015.02.025
关键词: Crystallography 、 Crystallization 、 Monoclinic crystal system 、 Derivative (chemistry) 、 Orthorhombic crystal system 、 Crystal structure 、 Ligand 、 Molecule 、 Inorganic chemistry 、 Chemistry 、 Pyridine
摘要: Abstract Two complexes of zinc phthalocyanine monoaxially ligated by 3,4-dimethylpyridine (1) and 4-ethylpyridine (2) were obtained in crystalline forms. Compound 1 depending on the crystallisation condition crystallises two modifications, i.e. monoclinic (P21/c, 1m) orthorhombic (Pccn, 1o), whereas compound 2 only one form (Pccn space system). Structures 1o are isotypic; an explanation that behaviour was proposed. Each structure contains ligand molecules molar ratio 1:1, which confirmed X-ray single diffraction thermogravimetric analysis. Ligation ZnPc N-ring aromatic ligands with formation does not change colouring properties, but increases their solubility organic solvents comparing to parent pigment.
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sci-hub.se 参考文章(21)
Robert G. Parr, Density-functional theory of atoms and molecules ,(1989)
Sílvia Simon, Miquel Duran, J. J. Dannenberg, How does basis set superposition error change the potential surfaces for hydrogen-bonded dimers? Journal of Chemical Physics. ,vol. 105, pp. 11024- 11031 ,(1996) , 10.1063/1.472902
Alexander Sorokin, Laurent Fraisse, Alain Rabion, Bernard Meunier, Metallophthalocyanine-catalyzed oxidation of catechols by H2O2 and its surrogates Journal of Molecular Catalysis A: Chemical. ,vol. 117, pp. 103- 114 ,(1997) , 10.1016/S1381-1169(96)00415-3
Xia Tao, Wanhong Ma, Tianyong Zhang, Jincai Zhao, A Novel Approach for the Oxidative Degradation of Organic Pollutants in Aqueous Solutions Mediated by Iron Tetrasulfophthalocyanine under Visible Light Radiation Chemistry: A European Journal. ,vol. 8, pp. 1321- 1326 ,(2002) , 10.1002/1521-3765(20020315)8:6<1321::AID-CHEM1321>3.0.CO;2-M
A. Sorokin, B. Meunier, J.-L. Seris, Efficient Oxidative Dechlorination and Aromatic Ring Cleavage of Chlorinated Phenols Catalyzed by Iron Sulfophthalocyanine Science. ,vol. 268, pp. 1163- 1166 ,(1995) , 10.1126/SCIENCE.268.5214.1163
Per. Sjoberg, Peter. Politzer, Use of the electrostatic potential at the molecular surface to interpret and predict nucleophilic processes The Journal of Physical Chemistry. ,vol. 94, pp. 3959- 3961 ,(1990) , 10.1021/J100373A017
Jan Janczak, Ryszard Kubiak, Jerzy Lisowski, Structural evidence of the formation of ZnPc-DBU complex during recrystallisation of commercially available ZnPc dye Polyhedron. ,vol. 30, pp. 253- 258 ,(2011) , 10.1016/J.POLY.2010.10.011
Alexander Sorokin, Sophie De Suzzoni-Dezard, Didier Poullain, Jean-Pierre Noël, Bernard Meunier, CO2as the Ultimate Degradation Product in the H2O2Oxidation of 2,4,6-Trichlorophenol Catalyzed by Iron Tetrasulfophthalocyanine Journal of the American Chemical Society. ,vol. 118, pp. 7410- 7411 ,(1996) , 10.1021/JA960177M
Chengteh Lee, Weitao Yang, Robert G. Parr, Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Physical Review B. ,vol. 37, pp. 785- 789 ,(1988) , 10.1103/PHYSREVB.37.785
Amanda L. Cashin, E. James Petersson, Henry A. Lester, Dennis A. Dougherty, Using Physical Chemistry To Differentiate Nicotinic from Cholinergic Agonists at the Nicotinic Acetylcholine Receptor Journal of the American Chemical Society. ,vol. 127, pp. 350- 356 ,(2005) , 10.1021/JA0461771