Thermal and Physical Properties of Molten Fluorides for Nuclear Applications
作者： J.P.M. van der Meer , R.J.M. Konings
DOI: 10.1016/J.JNUCMAT.2006.08.010
关键词: Thermodynamics 、 Vapor pressure 、 Work (thermodynamics) 、 Molten salt reactor 、 Mineralogy 、 Nuclear reactor 、 Phase (matter) 、 Viscosity 、 Thermal 、 Chemistry 、 Ternary numeral system
摘要: LiF–BeF2–ThF4 is a key system in molten salt reactor fuel studies. In this paper we give an overview of some important features ternary system. We discuss the phase behavior, vapor pressure, density and viscosity, based on what known literature our own data from previous work thermodynamic assessment LiF–BeF2–ThF4.
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F. Vaslow, A. H. Narten, Diffraction pattern and structure of molten BeF2–LiF solutions Journal of Chemical Physics. ,vol. 59, pp. 4949- 4954 ,(1973) , 10.1063/1.1680711
Yoshiyuki Abe, Otoya Kosugiyama, Akira Nagashima, Viscosity of LiF-BeF2 eutectic mixture (XBeF2 = 0.328) and LiF single salt at elevated temperatures Journal of Nuclear Materials. ,vol. 99, pp. 173- 183 ,(1981) , 10.1016/0022-3115(81)90186-0
D.G. Hill, S. Cantor, W.T. Ward, Molar volumes in the LiFThF4 system Journal of Inorganic and Nuclear Chemistry. ,vol. 29, pp. 241- 243 ,(1967) , 10.1016/0022-1902(67)80163-5
K. A. Romberger, J. Braustein, R. E. Thoma, New electrochemical measurements of the liquidus in the lithium fluoride-beryllium fluoride system. Congruency of lithium beryllium fluoride (Li2BeF4) The Journal of Physical Chemistry. ,vol. 76, pp. 1154- 1159 ,(1972) , 10.1021/J100652A012
J. D. Mackenzie, Structure of Glass Forming Halides. I. Liquid Beryllium Fluoride Journal of Chemical Physics. ,vol. 32, pp. 1150- 1152 ,(1960) , 10.1063/1.1730864
V. Ya. Chekhovskoi, A device for measuring the density and surface tension of melts Instruments and Experimental Techniques. ,vol. 43, pp. 415- 418 ,(2000) , 10.1007/BF02759049
J.P.M. van der Meer, R.J.M. Konings, M.H.G. Jacobs, H.A.J. Oonk, A miscibility gap in LiF–BeF2 and LiF–BeF2–ThF4 Journal of Nuclear Materials. ,vol. 344, pp. 94- 99 ,(2005) , 10.1016/J.JNUCMAT.2005.04.023
Cornelius T. Moynihan, Stanley Cantor, Viscosity and Its Temperature Dependence in Molten BeF2 Journal of Chemical Physics. ,vol. 48, pp. 115- 119 ,(1968) , 10.1063/1.1664455
V. N. Desyatnik, A. A. Klimenkov, N. N. Kurbatov, A. I. Nechaev, S. P. Raspopin, Yu. F. Chervinskii, Density and kinematic viscosity of NaF?ThF4 and KF?ThF4 melts Atomic Energy. ,vol. 51, pp. 807- 810 ,(1981) , 10.1007/BF01121687
C.W. Bale, P. Chartrand, S.A. Degterov, G. Eriksson, K. Hack, R. Ben Mahfoud, J. Melançon, A.D. Pelton, S. Petersen, FactSage thermochemical software and databases Calphad-computer Coupling of Phase Diagrams and Thermochemistry. ,vol. 26, pp. 189- 228 ,(2002) , 10.1016/S0364-5916(02)00035-4