Etching on polar (111) surfaces of CdTe crystals studied with Auger electron spectroscopy

作者: Y.‐C. Lu , C. M. Stahle , R. S. Feigelson , J. Morimoto

DOI: 10.1063/1.339033

关键词: Oxidizing agentHydrogenStoichiometryTelluriumAnalytical chemistrySingle crystalElectron spectroscopyAuger electron spectroscopyIsotropic etchingChemistry

摘要: Various reducing and oxidizing etches were applied to the polar (111)Cd (111)Te surfaces of CdTe crystals. The induced surface layers studied with Auger electron spectroscopy, chemical reactions involved discussed. A dithionite etch left both (111) Cd rich. sulfur in solution appeared replace Te near surface. hydrazine ratio about one on surfaces. large oxygen peak was observed increase as etching time temperature increased, indicating that not reducing. Hydrogen heat treatment stoichiometric, free contamination crystalline. best method we have tried retain stoichiometry (111)CdTe treated EAg‐1 rich, strong correlation between relative concentration Ag suggested a reaction Ag. Te(NOO)/Te(MNN) surf...

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