Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis
作者： Makoto Tokunaga , Jay F Larrow , Fumitoshi Kakiuchi , Eric N Jacobsen
DOI: 10.1126/SCIENCE.277.5328.936
关键词: Reagent 、 Organic chemistry 、 Diol 、 Enantioselective synthesis 、 Catalysis 、 Kinetic resolution 、 Enantiomer 、 Epoxide 、 Organic synthesis 、 Chemistry 、 Multidisciplinary
摘要: … by way of a hydrolytic kinetic resolution (HKR) using simple chiral catalysts (Scheme 1; … a significant level of epoxide hydrolysis competed with ring-opening by benzoic acid (Scheme 2; …
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