Stereoselective total syntheses of the naturally occurring enantiomers of N-acetylneuraminic acid and 3-deoxy-D-manno-2-octulosonic acid. A new and stereospecific approach to sialo and 3-deoxy-D-manno-2-octulosonic acid conjugates
作者： Samuel J. Danishefsky , Michael P. DeNinno , Shu Hui. Chen
DOI: 10.1021/JA00220A035
关键词: Stereospecificity 、 Enantiomer 、 Stereochemistry 、 2-Octulosonic acid 、 Glycoconjugate 、 Aliphatic compound 、 Conjugate 、 N-Acetylneuraminic acid 、 Chemistry 、 Stereoselectivity
摘要: Preparation de l'enantiomere naturel l'acide N-acetyl neuraminique a partir du phenylseleno-2 propanal et benzyloxy-4 [furyl-2]-1 methoxy-1 trimethylsiloxy-3 butadiene-«1,3». L'enantiomere KDO est obtenu propionate methyle
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