Proton conductive perovskite solid solutions with enhanced mechanical stability
作者： Thomas Matzke , Marcella Cappadonia
DOI: 10.1016/0167-2738(96)00231-7
关键词: Dielectric spectroscopy 、 Analytical chemistry 、 Inorganic chemistry 、 Solid solution 、 Hydrogen 、 Perovskite (structure) 、 Oxide 、 Electrolyte 、 Chemistry 、 Fast ion conductor 、 Conductivity
摘要: Abstract Perovskite solid solutions with formula SrYb0.05(Ce1 − xZrx)0.95O3 α (x = 0, 0.25, 0.5, 0.75 and 1) were prepared. Their electrical behaviour was investigated using impedance spectroscopy between 200 1000 °C in different atmospheres, without hydrogen. Conductivities their activation energies obtained. The perovskites showed a high mechanical stability considerable proton conductivity. Yb doped SrCe0.75Zr0.25O3 seems to be suitable electrolyte for oxide fuel cells.
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