Doping Graphitic and Carbon Nanotube Structures with Boron and Nitrogen

作者: O. Stephan , P. M. Ajayan , C. Colliex , Ph. Redlich , J. M. Lambert

DOI: 10.1126/SCIENCE.266.5191.1683

关键词: Interstitial compoundNitrogenBoronGraphiteCrystal structure of boron-rich metal boridesInorganic chemistryCarbonBoron nitrideMaterials scienceCarbon nanotube

摘要: Composite sheets and nanotubes of different morphologies containing carbon, boron, nitrogen were grown in the electric arc discharge between graphite cathodes amorphous boron-filled anodes a atmosphere. Concentration profiles derived from electron energy-loss line spectra show that boron are correlated one-to-one ratio; core fine structures reveal small differences compared to pure hexagonal nitride. Boron carbon anticorrelated, suggesting substitution into network. Results indicate singlephaase CyBxNx as well separated domains (nanosize) nitride networks may exist.

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