A Theory for the Estimation of Surface and Interfacial Energies. I. Derivation and Application to Interfacial Tension

作者: L. A. Girifalco , R. J. Good

DOI: 10.1021/J150553A013

关键词: Surface (mathematics)Surface tensionChemistryThermodynamics

摘要: There is, consequently, a great need for methods for the estimation of surface and interfacial ener-gies—even if only approximate ones. It was as an approach to these problems that the following treatment was developed. Theory of Interfacial Energies.—The Berthelot relation for the attractive constants between like molecules, Aaa and Abb, and that between unlike molecules A „b is3· 4

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