B–N compounds for chemical hydrogen storage

作者: Charles W. Hamilton , R. Tom Baker , Anne Staubitz , Ian Manners

DOI: 10.1039/B800312M

关键词: Storage materialGravimetric analysisDehydrogenation of amine-boranesChemistryAmmonia boraneInorganic chemistryOrganic chemistryN compoundsHydrogen storage

摘要: Hydrogen storage for transportation applications requires high volumetric and gravimetric capacity. B–N compounds are well suited as materials due to their light weight propensity bearing multiple protic (N–H) hydridic (B–H) hydrogens. This critical review briefly covers the various methods of hydrogen storage, then concentrates on chemical using compounds. The simplest compound, ammonia borane (H3NBH3), which has a potential 19.6 wt% capacity, will be emphasised (127 references).

参考文章(147)
Fengxiang X. Han, Jeff S. Lindner, Chuji Wang, Making carbon sequestration a paying proposition Naturwissenschaften. ,vol. 94, pp. 170- 182 ,(2007) , 10.1007/S00114-006-0170-6
Jun-Young Lee, Colin D. Wood, Darren Bradshaw, Matthew J. Rosseinsky, Andrew I. Cooper, Hydrogen adsorption in microporous hypercrosslinked polymers Chemical Communications. pp. 2670- 2672 ,(2006) , 10.1039/B604625H
P. Veeraraghavan Ramachandran, Pravin D. Gagare, Preparation of ammonia borane in high yield and purity, methanolysis, and regeneration. Inorganic Chemistry. ,vol. 46, pp. 7810- 7817 ,(2007) , 10.1021/IC700772A
Doris Pun, Emil Lobkovsky, Paul J. Chirik, Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes Chemical Communications. pp. 3297- 3299 ,(2007) , 10.1039/B704941B
Jun Li, Shawn M. Kathmann, Gregory K. Schenter, Maciej Gutowski, Isomers and conformers of H(NH2BH2)nH oligomers: Understanding the geometries and electronic structure of boron-nitrogen-hydrogen compounds as potential hydrogen storage materials Journal of Physical Chemistry C. ,vol. 111, pp. 3294- 3299 ,(2007) , 10.1021/JP066360B
Paul J. Fazen, Jeffrey S. Beck, Anne T. Lynch, Edward E. Remsen, Larry G. Sneddon, Thermally induced borazine dehydropolymerization reactions. Synthesis and ceramic conversion reactions of a new high-yield polymeric precursor to boron nitride Chemistry of Materials. ,vol. 2, pp. 96- 97 ,(1990) , 10.1021/CM00008A004
John L. Fulton, John C. Linehan, Tom Autrey, Mahalingam Balasubramanian, Yongsheng Chen, Nathaniel K. Szymczak, When is a Nanoparticle a Cluster? An Operando EXAFS Study of Amine Borane Dehydrocoupling by Rh4-6 Clusters Journal of the American Chemical Society. ,vol. 129, pp. 11936- 11949 ,(2007) , 10.1021/JA073331L
Akihiro Yamasaki, An overview of CO2 mitigation options for global warming -Emphasizing CO2 sequestration options Journal of Chemical Engineering of Japan. ,vol. 36, pp. 361- 375 ,(2003) , 10.1252/JCEJ.36.361
Roald Hoffmann, Extended Hückel Theory. III. Compounds of Boron and Nitrogen The Journal of Chemical Physics. ,vol. 40, pp. 2474- 2480 ,(1964) , 10.1063/1.1725550
Adam J. V. Marwitz, Eric R. Abbey, Jesse T. Jenkins, Lev N. Zakharov, Shih-Yuan Liu, Diversity through isosterism: the case of boron-substituted 1,2-dihydro-1,2-azaborines. Organic Letters. ,vol. 9, pp. 4905- 4908 ,(2007) , 10.1021/OL702383U