Stability of thin liquid films and sessile droplets under confinement.

作者: Fabian Dörfler , Markus Rauscher , S. Dietrich

DOI: 10.1103/PHYSREVE.88.012402

关键词: NanofluidicsDewettingChemical equilibriumInstabilityWettingNanotechnologyChemical physicsSpinodalDensity functional theoryMaterials scienceDrop (liquid)

摘要: The stability of nonvolatile thin liquid films and sessile droplets is strongly affected by finite size effects. We analyze their within the framework density functional theory using sharp kink approximation, i.e., on basis an effective interface Hamiltonian. show that effects suppress spinodal dewetting because it driven a long-wavelength instability. Therefore are stable if substrate area too small. Similarly, connected to wetting film become unstable large. This instability droplet turns out be equivalent volatile drop which can attain chemical equilibrium with its vapor.

参考文章(85)
Joel Louis Lebowitz, Cyril Domb, Melville S. Green, Phase Transitions and Critical Phenomena ,(1972)
Kajari Kargupta, Ashutosh Sharma, Creation of Ordered Patterns by Dewetting of Thin Films on Homogeneous and Heterogeneous Substrates Journal of Colloid and Interface Science. ,vol. 245, pp. 99- 115 ,(2002) , 10.1006/JCIS.2001.7860
Günter Reiter, Dewetting of Highly Elastic Thin Polymer Films Physical Review Letters. ,vol. 87, pp. 186101- ,(2001) , 10.1103/PHYSREVLETT.87.186101
Kenneth A. Brakke, The surface evolver Experimental Mathematics. ,vol. 1, pp. 141- 165 ,(1992) , 10.1080/10586458.1992.10504253
Kajari Kargupta, Ashutosh Sharma, Templating of Thin Films Induced by Dewetting on Patterned Surfaces Physical Review Letters. ,vol. 86, pp. 4536- 4539 ,(2001) , 10.1103/PHYSREVLETT.86.4536
M. Napiorkowski, L. Schimmele, S. Dietrich, S. Dietrich, Conceptual aspects of line tensions Journal of Chemical Physics. ,vol. 127, pp. 164715- 164715 ,(2007) , 10.1063/1.2799990
T. Getta, S. Dietrich, Line tension between fluid phases and a substrate Physical Review E. ,vol. 57, pp. 655- 671 ,(1998) , 10.1103/PHYSREVE.57.655
K. Jacobs, R. Seemann, S. Herminghaus, Dewetting patterns and molecular forces: a reconciliation. Physical Review Letters. ,vol. 86, pp. 5534- 5537 ,(2001) , 10.1103/PHYSREVLETT.86.5534
H.T. Dobbs, J.O. Indekeu, Line tension at wetting: interface displacement model beyond the gradient-squared approximation Physica A: Statistical Mechanics and its Applications. ,vol. 201, pp. 457- 481 ,(1993) , 10.1016/0378-4371(93)90120-S