Cathodoluminescence properties of La2MoO6:Ln3+ (Ln: Eu, Dy, and Sm) phosphors
作者： M. Ayvacikli , Ümit H. Kaynar , Y. Karabulut , J. Garcia Guinea , K. Bulcar
DOI: 10.1016/J.APRADISO.2020.109434
关键词: Ion 、 Spectroscopy 、 Materials science 、 Doping 、 Diffraction 、 Lanthanide 、 Phosphor 、 Analytical chemistry 、 Scanning electron microscope 、 Cathodoluminescence
摘要: Abstract La2MoO6 orange-red phosphors with high efficiency incorporated Eu, Dy and Sm have been synthesized through a gel combustion method. The influences of rare earth doping in samples were analysed by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), cathodoluminescence. Rare doped show strong emission bands the range 400–750 nm optimal concentration for all was 2 mol%. host Eu ion showed intense predominant peaks 450–750 nm range. electrical multipolar interaction contributed to non-radiative energy transfer between Eu3+ ions matrix. exhibited CL at 564, 608, 652 708 nm La2MoO6:Dy3+ phosphor displayed emissions 484, 574 670 nm, respectively. observed sharp indicate that is promising lanthanides materials applications optoelectronic.
sci-hub.st 参考文章(24)
E. Sani, A. Toncelli, M. Tonelli, D. A. Lis, E. V. Zharikov, K. A. Subbotin, V. A. Smirnov, Effect of cerium codoping in Er3+,Ce3+:NaLa(MoO4)2 crystals Journal of Applied Physics. ,vol. 97, pp. 123531- ,(2005) , 10.1063/1.1938276
M. Ayvacıklı, A. Ege, S. Yerci, N. Can, Synthesis and optical properties of Er3+ and Eu3+ doped SrAl2O4 phosphor ceramic Journal of Luminescence. ,vol. 131, pp. 2432- 2439 ,(2011) , 10.1016/J.JLUMIN.2011.05.051
Koen Binnemans, Peter Tom Jones, Bart Blanpain, Tom Van Gerven, Yiannis Pontikes, Towards zero-waste valorisation of rare-earth-containing industrial process residues: a critical review Journal of Cleaner Production. ,vol. 99, pp. 17- 38 ,(2015) , 10.1016/J.JCLEPRO.2015.02.089
J.A. Wani, N.S. Dhoble, S.P. Lochab, S.J. Dhoble, Luminescence characteristics of C5+ ions and 60Co irradiated Li2BaP2O7:Dy3+ phosphor Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 349, pp. 56- 63 ,(2015) , 10.1016/J.NIMB.2015.01.054
D Marrero-López, P Nunez, M Abril, V Lavin, UR Rodríguez-Mendoza, VD Rodríguez, None, Synthesis, electrical properties, and optical characterization of Eu3+-doped La2Mo2O9 nanocrystalline phosphors Journal of Non-crystalline Solids. ,vol. 345, pp. 377- 381 ,(2004) , 10.1016/J.JNONCRYSOL.2004.08.047
Dinesh K. Patel, Bathula Vishwanadh, Vasanthakumaran Sudarsan, Shailendra K. Kulshreshtha, Difference in the Nature of Eu3+ Environment in Eu3+‐Doped BaTiO3 and BaSnO3 Journal of the American Ceramic Society. ,vol. 96, pp. 3857- 3861 ,(2013) , 10.1111/JACE.12596
Xianghong He, Mingyun Guan, Chunyong Zhang, Tongming Shang, Ning Lian, Quanfa Zhou, Luminescence enhancement of Eu 3+ -activated La 2 Mo 2 O 9 red-emitting phosphor through chemical substitution Journal of Materials Research. ,vol. 26, pp. 2379- 2383 ,(2011) , 10.1557/JMR.2011.269
JMD Coey, Hong Sun, None, Improved magnetic properties by treatment of iron-based rare earth intermetallic compounds in anmonia Journal of Magnetism and Magnetic Materials. ,vol. 87, pp. L251- L254 ,(1990) , 10.1016/0304-8853(90)90756-G
I. Sabikoglu, M. Ayvacıklı, A. Bergeron, A. Ege, N. Can, Photoluminescence investigations of Li2SiO3:Ln (Ln = Er3+, Eu3+, Dy3+, Sm3+) phosphors Journal of Luminescence. ,vol. 132, pp. 1597- 1602 ,(2012) , 10.1016/J.JLUMIN.2012.02.008
Fangui MENG, Xinmin ZHANG, Huan LI, Hyo Jin Seo, Synthesis and spectral characteristics of La2MoO6:Ln3+ (Ln=Eu, Sm, Dy, Pr, Tb) polycrystals Journal of Rare Earths. ,vol. 30, pp. 866- 870 ,(2012) , 10.1016/S1002-0721(12)60147-1