Synthesis, characterisation and flame retardance behaviour of poly(ethylene terephthalate) copolymer containing triaryl phosphine oxide

作者: Li-Sheng Wang , Xin-Lan Wang , Gui-Lin Yan

DOI: 10.1016/S0141-3910(00)00050-1

关键词: CopolymerPhosphine oxidePolymer chemistryTolueneThermal stabilitySulfideCondensation polymerPhosphineMaterials scienceGlass transition

摘要: Bis 4-carboxyphenyl phenyl phosphine oxide (BCPPO) was prepared by oxidation of the corresponding dimethyl compound bis (4-methylphenyl) sulfide (prepared from reaction toluene with dichloro-phenyl sulfide). Flame resistant PET BCPPO as a co-monomer. The resulting copolymers exhibit good fibre-forming properties, improved flame retarding behaviour, high glass transition temperatures and thermal stability.

参考文章(5)
Y. Delaviz, A. Gungor, J.E. McGrath, H.W. Gibson, Soluble phosphine oxide containing aromatic polyamides Polymer. ,vol. 34, pp. 210- 213 ,(1993) , 10.1016/0032-3861(93)90308-W
Finn B. Jensen, The Tariff Question 1953 The Social Studies. ,vol. 44, pp. 260- 264 ,(1953) , 10.1080/00377996.1953.9957356
Chen-Chong Lin, Satish Baliga, A study on the polycondensation of bis‐hydroxyethyl terephthalate Journal of Applied Polymer Science. ,vol. 31, pp. 2483- 2489 ,(1986) , 10.1002/APP.1986.070310809
Paul W. Morgan, Barbara C. Herr, Some Dicarboxylic Acids and Esters Containing the Phosphine Oxide Group Journal of the American Chemical Society. ,vol. 74, pp. 4526- 4529 ,(1952) , 10.1021/JA01138A017