Synthesis and characterization of Ag–Ni bimetallic nanoparticles by laser-induced plasma

作者: Qingmei Xiao , Zhi Yao , Jiahong Liu , Ran Hai , Hassan Yousefi Oderji

DOI: 10.1016/J.TSF.2011.04.201

关键词: X-ray photoelectron spectroscopyRaman spectroscopyMass spectrometryNanoparticleLaser ablationBimetallic stripChemistryScanning electron microscopeChemical engineeringAnalytical chemistrySpectroscopy

摘要: Abstract We present an approach in which laser ablation deposition is used to synthesize silver–nickel bimetallic nanoparticles. A variety of techniques, including scanning electron microscopy, energy disperse spectroscopy and X-ray photoelectron have been characterize the morphology, composition construction synthesized nanoparticles, respectively. The formation mechanism nanoparticles has discussed. Raman spectra analyzed. Time-of-flight mass spectrometry applied directly measure intermediate species. results indicate that diatomic AgNi most abundant species suggest stable may play important role synthesis process. Emission demonstrate temperature range 6000–10000 K during process increases with power density.

参考文章(22)
D. Poondi, J. Singh, Synthesis of metastable silver-nickel alloys by a novel laser-liquid-solid interaction technique Journal of Materials Science. ,vol. 35, pp. 2467- 2476 ,(2000) , 10.1023/A:1004765618078
R. P. van Ingen, R. H. J. Fastenau, E. J. Mittemeijer, Formation of crystalline AgxNi1-x solid solutions of unusually high supersaturation by laser ablation deposition Physical Review Letters. ,vol. 72, pp. 3116- 3119 ,(1994) , 10.1103/PHYSREVLETT.72.3116
R. P. van Ingen, R. H. J. Fastenau, E. J. Mittemeijer, Laser ablation deposition of Cu‐Ni and Ag‐Ni films: Nonconservation of alloy composition and film microstructure Journal of Applied Physics. ,vol. 76, pp. 1871- 1883 ,(1994) , 10.1063/1.357711
G. Rossi, A. Rapallo, C. Mottet, A. Fortunelli, F. Baletto, R. Ferrando, Magic Polyicosahedral Core-Shell Clusters Physical Review Letters. ,vol. 93, pp. 105503- 105503 ,(2004) , 10.1103/PHYSREVLETT.93.105503
A. V. Sokolov, Optical Properties of Metals ,(1967)
M. Gaudry, E. Cottancin, M. Pellarin, J. Lermé, L. Arnaud, J. R. Huntzinger, J. L. Vialle, M. Broyer, J. L. Rousset, M. Treilleux, P. Mélinon, Size and composition dependence in the optical properties of mixed (transition metal/noble metal) embedded clusters Physical Review B. ,vol. 67, pp. 155409- ,(2003) , 10.1103/PHYSREVB.67.155409
J.A Aguilera, C. Aragón, Multi-element Saha–Boltzmann and Boltzmann plots in laser-induced plasmas Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 62, pp. 378- 385 ,(2007) , 10.1016/J.SAB.2007.03.024
Liu Jiahong, Xiao Qingmei, Wang Liping, Yao Zhi, Ding Hongbin, Laser-Ionization TOF Mass Spectrometer Characterization of Benzene Destruction in Atmospheric Pressure Pulsed Discharge Plasma Science & Technology. ,vol. 11, pp. 171- 176 ,(2009) , 10.1088/1009-0630/11/2/08
Sungsik Lee, Chaoyang Fan, Tianpin Wu, Scott L. Anderson, Cluster size effects on CO oxidation activity, adsorbate affinity, and temporal behavior of model Aun∕TiO2 catalysts The Journal of Chemical Physics. ,vol. 123, pp. 124710- 124710 ,(2005) , 10.1063/1.2035098