Evolution of microstructure and properties of phenolic fibers during carbonization
作者： Chun-Ling Liu , Wen-Sheng Dong , Jing-Ren Song , Lang Liu
DOI: 10.1016/J.MSEA.2007.02.067
关键词: Microstructure 、 Analytical chemistry 、 Thermogravimetric analysis 、 Materials science 、 Raman spectroscopy 、 Scanning electron microscope 、 Ultimate tensile strength 、 Infrared spectroscopy 、 Fourier transform infrared spectroscopy 、 Graphite
摘要: The microstructure evolution of phenolic fibers carbonized at different temperatures and the influence resulting on mechanical electrical behaviors were investigated using a combination techniques including thermogravimetric analysis-mass spectroscopy (TG-MS), Fourier transform infrared (FT-IR), laser Raman spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 physical adsorption, tensile strength conductivity measurements. results showed that below 500 ◦ C aromatic union was crosslinked by aliphatic bridges; above with increasing temperature polymer network destroyed, hexagonal carbon layers gradually formed; 850 content further increased due to transformation amorphous carbons in fibers; 1500 slow toward ideal graphite occurred. accessible micropores (<1.2 nm, 200–1040 m 2 /g) could be detected range 600–950 C. exhibited maximum value 640 MPa 550 electric reached 2.45 × 10 4 S/m 2800
elsevier.com
sci-hub.se 参考文章(32)
AKIFUMI ONODERA, KATSUTOMO TERASHIMA, TAKESHI URUSHIHARA, KAICHI SUITO, HITOSHI SUMIYA, SHUICHI SATOH, High-pressure synthesis of diamond from phenolic resin Journal of Materials Science. ,vol. 32, pp. 4309- 4318 ,(1997) , 10.1023/A:1018615705312
P. Gopal, L.R. Dharani, Frank D. Blum, Load, Speed and Temperature Sensitivities of a Carbon-Fiber-Reinforced Phenolic Friction Material Wear. pp. 913- 921 ,(1995) , 10.1016/0043-1648(95)90215-5
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
Nakorn Worasuwannarak, Shin Hatori, Hiroyuki Nakagawa, Kouichi Miura, Effect of oxidation pre-treatment at 220 to 270 °C on the carbonization and activation behavior of phenolic resin fiber Carbon. ,vol. 41, pp. 933- 944 ,(2003) , 10.1016/S0008-6223(02)00426-8
Hang Shi, Activated carbons and double layer capacitance Electrochimica Acta. ,vol. 41, pp. 1633- 1639 ,(1996) , 10.1016/0013-4686(95)00416-5
Shinn-Shyong Tzeng, Ya-Ga Chr, Evolution of microstructure and properties of phenolic resin-based carbon/carbon composites during pyrolysis Materials Chemistry and Physics. ,vol. 73, pp. 162- 169 ,(2002) , 10.1016/S0254-0584(01)00358-3
A Braun, M Bärtsch, B Schnyder, R Kötz, O Haas, H-G Haubold, G Goerigk, None, X-ray scattering and adsorption studies of thermally oxidized glassy carbon Journal of Non-crystalline Solids. ,vol. 260, pp. 1- 14 ,(1999) , 10.1016/S0022-3093(99)00571-2
V.V Strelko, V.S Kuts, P.A Thrower, On the mechanism of possible influence of heteroatoms of nitrogen, boron and phosphorus in a carbon matrix on the catalytic activity of carbons in electron transfer reactions Carbon. ,vol. 38, pp. 1499- 1503 ,(2000) , 10.1016/S0008-6223(00)00121-4
C.S. Tyberg, K. Bergeron, M. Sankarapandian, P. Shih, A.C. Loos, D.A. Dillard, J.E. McGrath, J.S. Riffle, U. Sorathia, Structure–property relationships of void-free phenolic–epoxy matrix materials Polymer. ,vol. 41, pp. 5053- 5062 ,(2000) , 10.1016/S0032-3861(99)00574-1
R.N Macnair, G.N Arons, L.G Coffin, Activated carbon fibers and fabrics Carbon. ,vol. 13, pp. 554- ,(1975) , 10.1016/0008-6223(75)90176-1