Iterative Dianion Relay Along the Ring: Formation of gem‐Bis(trimethylsilyl) Cyclopentenones from 2,5‐Bis(trimethylsilyl) Oxy‐cyclopentadienyl Dianions and Acid Chlorides
作者： Heng Li , Lantao Liu , Zitao Wang , Fei Zhao , Shaoguang Zhang
关键词: Cyclopentadienyl complex 、 Medicinal chemistry 、 Organic chemistry 、 Molecule 、 Stereoisomerism 、 Ring (chemistry) 、 Reactive intermediate 、 Chemistry 、 Trimethylsilyl
摘要:
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William H. Moser, Kezia E. Endsley, John T. Colyer, Stereoselective bis-functionalizations of arene chromium tricarbonyl complexes via brook rearrangements Organic Letters. ,vol. 2, pp. 717- 719 ,(2000) , 10.1021/OL0056022
H. Kwart, J. Slutsky, Unimolecular thermal rearrangement of allylsilanes. Sigmatropic 1,3 migration of silicon Journal of the American Chemical Society. ,vol. 94, pp. 2515- 2516 ,(1972) , 10.1021/JA00762A058
Isamu Matsuda, Shizuaki Murata, Yoshio Ishii, A simple preparation of trimethylsilylacetonitrile and a novel ring-opening of epoxides with trimethylsilylacetonitrile anion Journal of the Chemical Society, Perkin Transactions 1. ,vol. 10, pp. 26- 30 ,(1979) , 10.1039/P19790000026
Toshiaki Murai, Rumi Hori, Synthesis and Properties of Secondary Thiocarbamoylsilanes Bulletin of the Chemical Society of Japan. ,vol. 83, pp. 52- 57 ,(2010) , 10.1246/BCSJ.20090231
Yuan Mi, Jürg V. Schreiber, E. J. Corey, Total synthesis of (+)-α-onocerin in four steps via four-component coupling and tetracyclization steps Journal of the American Chemical Society. ,vol. 124, pp. 11290- 11291 ,(2002) , 10.1021/JA027373F
Bogdan M. Comanita, Simon Woo, Alex G. Fallis, A versatile tandem retro-[1,4]-Brook rearrangement-condensation reaction of o-bromoacetophenone silyl enol ethers Tetrahedron Letters. ,vol. 40, pp. 5283- 5286 ,(1999) , 10.1016/S0040-4039(99)00963-6
Kenichiro Itami, Koichi Mitsudo, Jun-ichi Yoshida, Facile generation of α-silyl carbanion of trimethylsilyl group assisted by intramolecular pyridyl group coordination Tetrahedron Letters. ,vol. 40, pp. 5533- 5536 ,(1999) , 10.1016/S0040-4039(99)01027-8
Amos B. Smith, Ming Xian, Won-Suk Kim, Dae-Shik Kim, The [1,5]-brook rearrangement : An initial application in anion relay chemistry Journal of the American Chemical Society. ,vol. 128, pp. 12368- 12369 ,(2006) , 10.1021/JA065033E
Kei Takeda, Daisuke Nakane, Mika Takeda, Synthesis of the Tricyclic Skeleton of Cyathins Using Brook Rearrangement-Mediated [3 + 4] Annulation Organic Letters. ,vol. 2, pp. 1903- 1905 ,(2000) , 10.1021/OL0059753
Amos B. Smith, Megan A. Foley, Shuzhi Dong, Alia Orbin, (+)-Rimocidin synthetic studies: construction of the C(1-27) aglycone skeleton. Journal of Organic Chemistry. ,vol. 74, pp. 5987- 6001 ,(2009) , 10.1021/JO900765P