Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst

作者: Gregory F. Schmidt , Maurice Brookhart

DOI: 10.1021/JA00291A073

关键词: CatalysisAlkylElectronActivation energyChemistryEthylene polymerizationPolymerizationEthylenePolymer chemistryPhotochemistry

摘要: On propose l'existence d'une parallele entre la structure et dynamique des complexes hydrures les energies d'activation pour reactions de migration d'alkyle leurs analogues alkyle

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