The electrocatalytic activity of Ni(II)/Ni(III) oxide films in alkaline solutions
作者： RE Carbonio , VA Macagno , AJ Arvia
DOI: 10.1016/S0022-0728(83)80062-X
关键词: Hydroxide 、 Chemistry 、 Carbon 、 Platinum 、 Inorganic chemistry 、 Catalysis 、 Oxide 、 Nickel 、 Precipitation (chemistry) 、 Substrate (chemistry)
摘要: Abstract The reactions involved in the electroreduction and electroformation of O2 on electrodes prepared by precipitation nickel hydroxide different conducting substrates (platinum or vitreous carbon) alkaline solutions are investigated. catalytic activity these for evolution reaction is independent nature substrate but depends ageing conditions hydroxide. mechanisms explained through participation both Ni(III) very reactive Ni(IV) species. electrocatalytic related to u-NiOOH occurs surface mainly determined characteristic substrate.
elsevier.com
sci-hub.se 参考文章(19)
ME Folquer, JR Vilche, A_J Arvia, Electrochemical Reactions at Multiple Interfaces The Nickel Hydroxide Electrode Formed by Precipitation on a Platinum Surface Journal of The Electrochemical Society. ,vol. 127, pp. 2634- 2640 ,(1980) , 10.1149/1.2129536
P. W. T. Lu, S. Srinivasan, Electrochemical‐Ellipsometric Studies of Oxide Film Formed on Nickel during Oxygen Evolution Journal of The Electrochemical Society. ,vol. 125, pp. 1416- 1422 ,(1978) , 10.1149/1.2131689
I. Morcos, E. Yeager, Kinetic studies of the oxygen—peroxide couple on pyrolytic graphite Electrochimica Acta. ,vol. 15, pp. 953- 975 ,(1970) , 10.1016/0013-4686(70)80037-8
H. Bode, K. Dehmelt, J. Witte, Zur kenntnis der nickelhydroxidelektrode—I.Über das nickel (II)-hydroxidhydrat Electrochimica Acta. ,vol. 11, pp. 1079- 1087 ,(1966) , 10.1016/0013-4686(66)80045-2
Donald Tuomi, The Forming Process in Nickel Positive Electrodes Journal of The Electrochemical Society. ,vol. 112, pp. 1- 12 ,(1965) , 10.1149/1.2423457
H. G�mez Meier, J. R. Vilche, A. J. Arvia, The influence of temperature on the current peak multiplicity related to the nickel hydroxide electrode Journal of Applied Electrochemistry. ,vol. 10, pp. 611- 621 ,(1980) , 10.1007/BF00615484
RS Schrebler Guzmán, JR Vilche, AJ Arvia, Electrochemical and chemical reactions involving non-equilibrium species at the nickel hydroxide electrode Journal of Applied Electrochemistry. ,vol. 9, pp. 321- 327 ,(1979) , 10.1007/BF01112486
Keith E. Gubbins, Robert D. Walker, The Solubility and Diffusivity of Oxygen in Electrolytic Solutions Journal of The Electrochemical Society. ,vol. 112, pp. 469- 471 ,(1965) , 10.1149/1.2423575
D.B. Sepa, M.V. Vojnovic, A. Damjanovic, Kinetics and mechanism of O2 reduction at Pt IN alkaline solutions Electrochimica Acta. ,vol. 25, pp. 1491- 1496 ,(1980) , 10.1016/0013-4686(80)87167-2
Jorge Roberto Vilche, Alejandro Jorge Arvia, Kinetics and mechanism of the nickel electrode—II. Acid solutions containing a high concentration of sulphate and nickel ions Corrosion Science. ,vol. 18, pp. 441- 463 ,(1978) , 10.1016/S0010-938X(78)80039-0