The thermodynamic properties of fluorocarbon+hydrocarbon mixtures 2. Excess enthalpies of mixing

作者: A Andrews , K.W Morcom , W.A Duncan , F.L Swinton , J.M Pollock

DOI: 10.1016/0021-9614(70)90068-6

关键词: Hydrocarbon mixturesHexafluorobenzeneEnthalpy of mixingHydrocarbonMixing (process engineering)ChemistryThermodynamicsAlicyclic compoundFluorocarbonChemical substance

摘要: Abstract The enthalpy of mixing hexafluorobenzene with a series alicyclic and aromatic hydrocarbons has been measured as function temperature and, in many cases, over the whole range compositions. excess heat capacity mixtures calculated for equimolar mixtures. results indicate that it is shape hydrocarbon predominant factor governing magnitude functions π-π interactions play secondary role this respect.

参考文章(15)
C. R. PATRICK, G. S. PROSSER, A Molecular Complex of Benzene and Hexafluorobenzene Nature. ,vol. 187, pp. 1021- 1021 ,(1960) , 10.1038/1871021A0
Arvind P. Kudchadker, Ghalib H. Alani, Bruno J. Zwolinski, Critical Constants of Organic Substances Chemical Reviews. ,vol. 68, pp. 659- 735 ,(1968) , 10.1021/CR60256A002
F. L. Swinton, W. A. Duncan, J. P. Sheridan, Thermodynamic properties of binary systems containing hexafluorobenzene. Part 2.—Excess volumes of mixing and dipole moments Transactions of The Faraday Society. ,vol. 62, pp. 1090- 1096 ,(1966) , 10.1039/TF9666201090
M. Lal, F.L. Swinton, The thermodynamic properties of the binary mixtures benzene/benzene-d6 and cyclohexane/cyclohexane-d12 Physica D: Nonlinear Phenomena. ,vol. 40, pp. 446- 452 ,(1968) , 10.1016/0031-8914(68)90140-7
D. L. Andersen, R. A. Smith, D. B. Myers, S. K. Alley, A. G. Williamson, R. L. Scott, A THERMODYNAMIC STUDY OF THE SYSTEM 1-HYDRO-n-PERFLUOROHEPTANE + ACETONE1 The Journal of Physical Chemistry. ,vol. 66, pp. 621- 624 ,(1962) , 10.1021/J100810A012
D. A. Armitage, K. W. Morcom, Thermodynamic behaviour of mixtures of hexafluorobenzene with amines. Part 1.—Enthalpies of mixing Trans. Faraday Soc.. ,vol. 65, pp. 688- 695 ,(1969) , 10.1039/TF9696500688
David V. Fenby, Robert Lane Scott, Heats of mixing of nonelectrolyte solutions. IV. Mixtures of fluorinated benzenes The Journal of Physical Chemistry. ,vol. 71, pp. 4103- 4110 ,(1967) , 10.1021/J100871A058
J. A. Larkin, M. L. McGlashan, 666. A new calorimeter for heats of mixing. The heat of mixing of benzene with carbon tetrachloride Journal of the Chemical Society (Resumed). pp. 3425- 3432 ,(1961) , 10.1039/JR9610003425
M. L. McGlashan, D. Stubley, Harry Watts, Enthalpies of mixing and complex formation of carbon tetrachloride with benzene, toluene, p-xylene, and mesitylene Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 673- 678 ,(1969) , 10.1039/J19690000673