Application of the Nuclear Magnetic Resonance to the Study of the Superficial Constitutive Water of Titanium Oxides

作者: M. A. Enriquez , C. Dorémieux-Morin , J. Fraissard

DOI: 10.1007/978-94-009-9079-1_29

关键词: AnataseTitaniumLattice (order)Amorphous solidShape functionRutileMaterials scienceNuclear magnetic resonance

摘要: The superficial constitutive water of titanium oxides (rutile, anatase and amorphous) has been studied by NMR in “rigid lattice” conditions. For these three solids, spectral interpretation shape function calculation leads to a distribution protons between molecular OH groups characteristic distances that we compare.

参考文章(12)
E. R. Andrew, R. Bersohn, Nuclear Magnetic Resonance Line Shape for a Triangular Configuration of Nuclei The Journal of Chemical Physics. ,vol. 18, pp. 159- 161 ,(1950) , 10.1063/1.1747579
B. Pedersen, D. F. Holcomb, NMR in Hydrate Crystals: Structural Information from Broadened Fine‐Structure Lines The Journal of Chemical Physics. ,vol. 38, pp. 61- 69 ,(1963) , 10.1063/1.1733496
R STEVENSON, The location of the protons in dehydrated Y-faujasite Journal of Catalysis. ,vol. 21, pp. 113- 121 ,(1971) , 10.1016/0021-9517(71)90127-8
R. E. Richards, J. A. S. Smith, Erratum: nuclear magnetic resonance spectra of some acid hydrates Transactions of the Faraday Society. ,vol. 48, pp. 675- 675 ,(1952) , 10.1039/TF9524800675
E R Andrew, N D Finch, Nuclear Magnetic Resonance Spectrum for Isosceles Triangular Configurations of Nuclei Proceedings of the Physical Society. Section B. ,vol. 70, pp. 980- 990 ,(1957) , 10.1088/0370-1301/70/10/307
G. E. Pake, Nuclear Resonance Absorption in Hydrated Crystals: Fine Structure of the Proton Line The Journal of Chemical Physics. ,vol. 16, pp. 327- 336 ,(1948) , 10.1063/1.1746878
D. F. Holcomb, B. Pedersen, Structural Interpretation of Asymmetrically Broadened NMR Fine‐Structure Lines The Journal of Chemical Physics. ,vol. 38, pp. 54- 60 ,(1963) , 10.1063/1.1733495
Bjørn Pedersen, Bo Sjöberg, Krister Fontell, Charles Larsen, Carl Th. Pedersen, Ulf Rosén, Least Squares Analysis of NMR-Spectra of Pair-Powders. Acta Chemica Scandinavica. ,vol. 22, pp. 444- 452 ,(1968) , 10.3891/ACTA.CHEM.SCAND.22-0444
Joël Kermarec, Jacques Fraissard, Jean Elston, Boris Imelik, N° 81. — Application de la résonance magnétique nucléaire à l’étude de l’eau de constitution des solides divisés: II. -— Silice-alumine Journal de Chimie Physique. ,vol. 65, pp. 920- 925 ,(1968) , 10.1051/JCP/1968650920