Use of metallated allylic ethers for the elaboration of vicinally trisubstituted linear substrates or cyclopropyl carbinols
作者： Franck Ferreira , Christelle Herse , Eric Riguet , Jean F Normant
DOI: 10.1016/S0040-4039(00)00025-3
关键词: Reagent 、 Cyclopropanation 、 Zinc 、 Allylic rearrangement 、 Chemistry 、 Organic chemistry
摘要: Abstract Allyl zinc reagents derived from allylic ethers carbometallate vinyllithiums secondary ethers, leading to linear 3,5-dialkoxy-4-methyl-1-alkenes, or 1-vinyl-2-alkoxyalkyl cyclopropanes diastereoselectively.
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