Mössbauer Effect Study of α-FeOOH and β-FeOOH; Making Use of Oriented Particles

作者: Naoichi Yamamoto , Teruya Shinjo , Masao Kiyama , Yoshichika Bando , Toshio Takada

DOI: 10.1143/JPSJ.25.1267

关键词: CrystalMössbauer effectAbsorption spectroscopyParamagnetismAnalytical chemistryAntiferromagnetismMaterials scienceElectric field gradientMössbauer spectroscopyQuadrupoleCondensed matter physicsGeneral Physics and Astronomy

摘要: Mossbauer absorption spectra were measured for oriented samples of α- and β-FeOOH particles at antiferromagnetic paramagnetic states, which prepared utilizing the anisotropic particle shape. Considering intensity ratio six peaks, direction electron spin in state was concluded to be parallel crystal c -axis each compound. From quadrupole doublet, electric field gradient discussed. The axis estimated -plane.

参考文章(10)
I. Dézsi, L. Keszthelyi, D. Kulgawczuk, B. McInár, N. A. Eissa, Mössbauer Study of β- and δ-FeOOH and their Disintegration Products physica status solidi (b). ,vol. 22, pp. 617- 629 ,(1967) , 10.1002/PSSB.19670220234
D.S. Kulgawczuk, K. Tomala, A.Z. Hrynkiewicz, Antiferromagnetism of α-FeOOH investigated with the Mössbauer effect Physics Letters. ,vol. 17, pp. 93- 95 ,(1965) , 10.1016/0031-9163(65)90249-0
Hiroki Miyamoto, Teruya Shinjo, Yoshichika Bando, Toshio Takada, Mössbauer Effect of Fe57 in Fe(OH)2 Journal of the Physical Society of Japan. ,vol. 23, pp. 1421- 1421 ,(1967) , 10.1143/JPSJ.23.1421
Teruya Shinjo, Mössbauer Effect in Antiferromagnetic Fine Particles Journal of the Physical Society of Japan. ,vol. 21, pp. 917- 922 ,(1966) , 10.1143/JPSJ.21.917
A.M. van der Kraan, J.J. van Loef, Superparamagnetism in submicroscopic α-FeOOH particles observed by the Mössbauer effect Physics Letters. ,vol. 20, pp. 614- 616 ,(1966) , 10.1016/0031-9163(66)91140-1
John H. L. Watson, R. R. Cardell, Wilfried Heller, THE INTERNAL STRUCTURE OF COLLOIDAL CRYSTALS OF β-FeOOH AND REMARKS ON THEIR ASSEMBLIES IN SCHILLER LAYERS The Journal of Physical Chemistry. ,vol. 66, pp. 1757- 1763 ,(1962) , 10.1021/J100816A001
M.J. Rossiter, A.E.M. Hodgson, A Mössbauer study of ferric oxy-hydroxide Journal of Inorganic and Nuclear Chemistry. ,vol. 27, pp. 63- 71 ,(1965) , 10.1016/0022-1902(65)80191-9
Toshio Takada, Masao Kiyama, Yoshichika Bando, Takashi Nakamura, Masayuki Shiga, Teruya Shinjo, Naoichi Yamamoto, Yasuo Endoh, Hideo Takaki, Mössbauer Study of a-, β- and γ-FeOOH Journal of the Physical Society of Japan. ,vol. 19, pp. 1744- 1744 ,(1964) , 10.1143/JPSJ.19.1744
I. Dézsi, M. Fodor, On the Antiferromagnetism of α-FeOOH physica status solidi (b). ,vol. 15, pp. 247- 254 ,(1966) , 10.1002/PSSB.19660150124