Co-electrospinning fabrication and photocatalytic performance of TiO2/SiO2 core/sheath nanofibers with tunable sheath thickness

作者: Houbao Cao , Pingfan Du , Lixin Song , Jie Xiong , Junjie Yang

DOI: 10.1016/J.MATERRESBULL.2013.08.035

关键词: SilanolX-ray photoelectron spectroscopyFourier transform infrared spectroscopyElectrospinningPhotocatalysisMaterials scienceNanofiberNanotechnologyChemical engineeringCalcinationAmorphous solid

摘要: Abstract In this paper, core/sheath TiO 2 /SiO nanofibers with tunable sheath thickness were directly fabricated via a facile co-electrospinning technique subsequent calcination at 500 °C. The morphologies and structures of characterized by TGA, FESEM, TEM, FTIR, XPS BET. It was found that the 1D are made up anatase–rutile core amorphous SiO sheath. influences its on photoreactivity evaluated observing photo-degradation methylene blue aqueous solution under irradiation UV light. Compared pure nanofibers, performed better catalytic performance. That attributed to not only efficient separation hole–electron pairs resulting from formation heterojunction but also larger surface area silanol group which will be useful provide higher capacity for oxygen adsorption generate more hydroxyl radicals. And optimized 37 nm exhibited best photocatalytic

参考文章(44)
Jiandong Fan, Reza Zamani, Cristian Fábrega, Alexey Shavel, Cristina Flox, Maria Ibáñez, Teresa Andreu, Antonio M López, Jordi Arbiol, Joan Ramón Morante, Andreu Cabot, Solution-growth and optoelectronic performance of ZnO : Cl/TiO2 and ZnO : Cl/ZnxTiOy/TiO2 core–shell nanowires with tunable shell thickness Journal of Physics D. ,vol. 45, pp. 415301- ,(2012) , 10.1088/0022-3727/45/41/415301
Akash Katoch, Sang Sub Kim, Synthesis of Hollow Silica Fibers with Porous Walls by Coaxial Electrospinning Method Journal of the American Ceramic Society. ,vol. 95, pp. 553- 556 ,(2012) , 10.1111/J.1551-2916.2011.04923.X
Ningning Yan, Zhongqi Zhu, Jin Zhang, Zongyan Zhao, Qingju Liu, Preparation and properties of ce-doped TiO2 photocatalyst Materials Research Bulletin. ,vol. 47, pp. 1869- 1873 ,(2012) , 10.1016/J.MATERRESBULL.2012.04.077
Chuanhong Kang, Liqiang Jing, Tong Guo, Hucheng Cui, Jia Zhou, Honggang Fu, Mesoporous SiO2-Modified Nanocrystalline TiO2 with High Anatase Thermal Stability and Large Surface Area as Efficient Photocatalyst Journal of Physical Chemistry C. ,vol. 113, pp. 1006- 1013 ,(2009) , 10.1021/JP807552U
Pingfan Du, Lixin Song, Jie Xiong, Yongfeng Yuan, Longcheng Wang, Zhenqiang Xi, Dalai Jin, Jianjun Chen, TiO2/Nb2O5 core–sheath nanofibers film: Co-electrospinning fabrication and its application in dye-sensitized solar cells Electrochemistry Communications. ,vol. 25, pp. 46- 49 ,(2012) , 10.1016/J.ELECOM.2012.09.013
Thirumal Krishnamoorthy, Velmurugan Thavasi, Mhaisalkar Subodh G, Seeram Ramakrishna, A first report on the fabrication of vertically aligned anatase TiO2 nanowires by electrospinning: Preferred architecture for nanostructured solar cells Energy and Environmental Science. ,vol. 4, pp. 2807- 2812 ,(2011) , 10.1039/C1EE01315G
Sung Wook Lee, Young Un Kim, Sung-Seen Choi, Tae Young Park, Yong Lak Joo, Seung Goo Lee, Preparation of SiO2/TiO2 composite fibers by sol–gel reaction and electrospinning Materials Letters. ,vol. 61, pp. 889- 893 ,(2007) , 10.1016/J.MATLET.2006.06.020
Daniel A. Higgins, Shannon K. Byerly, Michael B. Abrams, Robert M. Corn, Second harmonic generation studies of methylene blue orientation at silica surfaces The Journal of Physical Chemistry. ,vol. 95, pp. 6984- 6990 ,(1991) , 10.1021/J100171A048
Suxia Ren, Xu Zhao, Lina Zhao, Meirong Yuan, Yang Yu, Yupeng Guo, Zichen Wang, Preparation of porous TiO2/silica composites without any surfactants Journal of Solid State Chemistry. ,vol. 182, pp. 312- 316 ,(2009) , 10.1016/J.JSSC.2008.10.027
S. Wang, J.S. Lian, W.T. Zheng, Q. Jiang, Photocatalytic property of Fe doped anatase and rutile TiO2 nanocrystal particles prepared by sol–gel technique Applied Surface Science. ,vol. 263, pp. 260- 265 ,(2012) , 10.1016/J.APSUSC.2012.09.040