Water-mediated promotion of direct oxidation of benzene over the metal–organic framework HKUST-1
作者： Yanfeng Liu , Tianyong Zhang , Wubin Wu , Shuang Jiang , Hao Zhang
DOI: 10.1039/C5RA05595D
关键词: Selectivity 、 Water treatment 、 Benzene 、 Catalytic oxidation 、 Hydrogen peroxide 、 Hydroquinone 、 Chemistry 、 Organic chemistry 、 Phenol 、 Catalysis
摘要: Pretreatment of a HKUST-1 catalyst with water significantly accelerated the catalytic oxidation benzene to phenol and hydroquinone hydrogen peroxide as an oxidant. The corresponding oxygenates had yield 36.5%, selectivity was 53.2% 35.5%, respectively. turnover frequency (TOF) 35.1 h−1. Comparatively, product only 2.7% over original HKUST-1, TOF 2.6 Moreover, treatment protected from decomposition due formation new mode. Therefore, system in presence opened door towards facile efficient preparation hydroquinone.
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