Spectroscopic study of the self-assembly behavior of a vertical soap film stabilized with cetyltrimethylammonium bromide and Thiazole Yellow

作者: Xuezhong Du , Yingqiu Liang

DOI: 10.1039/A909317F

关键词: BromideAqueous solutionSelf-assemblyChemistryMonolayerCationic polymerizationPulmonary surfactantChemical engineeringSoap filmFourier transform infrared spectroscopyOrganic chemistry

摘要: FTIR and UV-vis spectroscopy were used to investigate the thinning process self-assembly behavior of a stable black soap film (BSF) prepared from cationic surfactant cetyltrimethylammonium bromide anionic dye Thiazole Yellow (TY) in a micellar phase. During course thinning, construction two monolayers is nearly independent aqueous core thickness, indicating feature BSF. At equilibrium, thickness estimated be approximately 1.7 nm, TY molecules are aligned parallel plane form J-aggregate with concentration 190 times higher than that film-forming solution.

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