METAL-INORGANIC FRAMEWORKS

作者: Mohammad A. Omary , Joshua F. Ivy

DOI:

关键词: Combinatorial chemistryChemistryChemical structureMoleculeSelectivityAdsorptionCatalysisThermal stabilityMetalHydrogen

摘要: Metal-inorganic frameworks (“MIFs”) having enhanced adsorption capabilities to hydrogen, CO, CO2, hydrocarbons, and a variety of other guest molecules are disclosed. All linkers in the MIFs contain metal complexes, comprising atoms inorganic or organic ligands, instead only ligands as metal-organic (MOFs). Compared their MOF counterparts, with carbon-free carbon-deficient chemical structure expected possess thermal stability, higher catalytic activity, gas affinity selectivity.

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