作者: Mohammad A. Omary , Joshua F. Ivy
DOI:
关键词: Combinatorial chemistry 、 Chemistry 、 Chemical structure 、 Molecule 、 Selectivity 、 Adsorption 、 Catalysis 、 Thermal stability 、 Metal 、 Hydrogen
摘要: Metal-inorganic frameworks (“MIFs”) having enhanced adsorption capabilities to hydrogen, CO, CO2, hydrocarbons, and a variety of other guest molecules are disclosed. All linkers in the MIFs contain metal complexes, comprising atoms inorganic or organic ligands, instead only ligands as metal-organic (MOFs). Compared their MOF counterparts, with carbon-free carbon-deficient chemical structure expected possess thermal stability, higher catalytic activity, gas affinity selectivity.