Polyacetylene in Diamond Films Evidenced by Surface Enhanced Raman Scattering

作者: T. López-Ríos , É. Sandré , S. Leclercq , É. Sauvain

DOI: 10.1103/PHYSREVLETT.76.4935

关键词: Chemical vapor depositionOpticsPolyacetyleneExcitationX-ray Raman scatteringHigh-resolution transmission electron microscopyDiamondRaman scatteringRaman spectroscopyAnalytical chemistryMaterials science

摘要: Trans-polyacetylene is evidenced by surface enhanced Raman scattering (SERS) in diamond films prepared hot filament assisted chemical vapor deposition from C${\mathrm{H}}_{4}$ and ${\mathrm{H}}_{2}$. The analysis of the spectra for different excitation energies shows that deposited trans-polyacetylene composed chains exhibiting short conjugation lengths. Together with polyacetylene, crystals nanometric dimension are both SERS high resolution transmission electron microscopy.

参考文章(20)
J. C. ANGUS, C. C. HAYMAN, Low-Pressure, Metastable Growth of Diamond and "Diamondlike" Phases Science. ,vol. 241, pp. 913- 921 ,(1988) , 10.1126/SCIENCE.241.4868.913
W. A. Yarbrough, R. Messier, Current Issues and Problems in the Chemical Vapor Deposition of Diamond Science. ,vol. 247, pp. 688- 696 ,(1990) , 10.1126/SCIENCE.247.4943.688
Qi Lichang, Xuan Zhenwu, Yang Peichun, Pu Xin, Hou Li, Presence of core particles in diamond crystals grown by electron assisted chemical vapor deposition Journal of Crystal Growth. ,vol. 112, pp. 580- 582 ,(1991) , 10.1016/0022-0248(91)90337-5
Diane S. Knight, Ronald Weimer, Lawrence Pilione, William B. White, Surface‐enhanced Raman spectroscopy of chemical vapor deposited diamond films Applied Physics Letters. ,vol. 56, pp. 1320- 1322 ,(1990) , 10.1063/1.102505
Yasushi Muranaka, Hisao Yamashita, Hiroshi Miyadera, Synthesis and purification of diamond films using the microwave plasma of a CO-H2 system Journal of Materials Science. ,vol. 26, pp. 3235- 3243 ,(1991) , 10.1007/BF01124667
Yasushi Muranaka, Hisao Yamashita, Hiroshi Miyadera, Characterization of diamond films synthesized in the microwave plasmas of CO/H2 and CO/O2/H2 systems at low temperatures (403–1023 K) Journal of Applied Physics. ,vol. 69, pp. 8145- 8153 ,(1991) , 10.1063/1.347468
Ichiro Watanabe, Ken Sugata, ESR in Diamond Thin Films Synthesized by Microwave Plasma Chemical Vapor Deposition Japanese Journal of Applied Physics. ,vol. 27, pp. 1808- 1811 ,(1988) , 10.1143/JJAP.27.1808
R. J. Nemanich, J. T. Glass, G. Lucovsky, R. E. Shroder, Raman scattering characterization of carbon bonding in diamond and diamondlike thin films Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. ,vol. 6, pp. 1783- 1787 ,(1988) , 10.1116/1.575297
J. Wagner, C. Wild, P. Koidl, Resonance effects in Raman scattering from polycrystalline diamond films Applied Physics Letters. ,vol. 59, pp. 779- 781 ,(1991) , 10.1063/1.105340
B. Marcus, L. Fayette, M. Mermoux, L. Abello, G. Lucazeau, Analysis of the structure of multi‐component carbon films by resonant Raman scattering Journal of Applied Physics. ,vol. 76, pp. 3463- 3470 ,(1994) , 10.1063/1.357476