Coordination compound films of 1-phenyl-5-mercaptotetrazole on copper surface
作者： X.R Ye , X.Q Xin , J.J Zhu , Z.L Xue
DOI: 10.1016/S0169-4332(98)00301-8
关键词: Copper 、 Auger electron spectroscopy 、 Linear sweep voltammetry 、 Nuclear chemistry 、 X-ray photoelectron spectroscopy 、 Benzotriazole 、 Infrared spectroscopy 、 Chemistry 、 Cyclic voltammetry 、 Hydroxybenzotriazole 、 Analytical chemistry
摘要: Abstract The chemical nature of the coordination compound film formed by reacting PMTA (1-phenyl-5-mercaptotetrazole) with a copper surface has been studied accelerated corrosion tests, linear sweep voltammetry (LSV), cyclic (CV), Fourier-transform infrared spectroscopy (FT-IR), X-ray photoelectron (XPS) and Auger electron (AES). These studies show that, in retarding substrate, is superior to those TTA (tetrazole), BTA (benzotriazole), HBTA (hydroxybenzotriazole), MBT (2-mercaptobenzothiazole), MBI (2-mercaptobenzo-imidazole), 2-AP (2-aminopyrimidine), IBM (imidazole) chromates. characterized found be polymeric complex Cu–PMTA. mechanism for formation relationships between this novel structure observed inhibition behavior are discussed.
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