Amperometric Glucose Sensor Based on Glucose Oxidase Immobilized on Conducting Organic Salt Electrode by Poly(o-Phenylenediamine) Film
作者： D. Centonze , C. Malitesta , F. Palmisano , P.G. Zambonin
DOI: 10.1016/B978-1-85617-242-4.50011-2
关键词: Biosensor 、 Materials science 、 Membrane 、 Limiting oxygen concentration 、 Electrode 、 Nuclear chemistry 、 Glucose oxidase 、 Oxygen 、 Amperometry 、 Chromatography 、 Fluorescent glucose biosensor
摘要: This chapter discusses amperometric glucose sensor based on oxidase immobilized conducting organic salt electrode by poly( o -phenylenediamine) film. The response of an biosensor ultimately relies detection H 2 O produced the natural mediator in course enzyme regeneration. As a result, is affected oxygen concentration. It was demonstrated that effectiveness new approach use electrochemically grown non-conducting films as entrapping membrane. These show unique permselectivity and antifouling properties permit one step construction sensors having fast response, high sensitivity, low interference. To overcome problem dependence, has been poly- -phenylenediamine film NMP-TCNQ electrode. shows good sensitivity interferent rejection. In range concentration values typical blood, exhibits dependence.
sci-hub.st 参考文章(5)
W.John Albery, Philip N. Bartlett, Derek H. Craston, Amperometric enzyme electrodes: Part II. Conducting salts as electrode materials for the oxidation of glucose oxidase Journal of Electroanalytical Chemistry. ,vol. 194, pp. 223- 235 ,(1985) , 10.1016/0022-0728(85)85006-3
Jodi L. Kawagoe, David E. Niehaus, R. Mark. Wightman, Enzyme-modified organic conducting salt microelectrode Analytical Chemistry. ,vol. 63, pp. 2961- 2965 ,(1991) , 10.1021/AC00024A029
Cosimino. Malitesta, Francesco. Palmisano, Luisa. Torsi, Pier Giorgio. Zambonin, Glucose fast-response amperometric sensor based on glucose oxidase immobilized in an electropolymerized poly(o-phenylenediamine) film Analytical Chemistry. ,vol. 62, pp. 2735- 2740 ,(1990) , 10.1021/AC00223A016
Anthony E. G. Cass, Graham. Davis, Graeme D. Francis, H. Allen O. Hill, William J. Aston, I. John. Higgins, Elliot V. Plotkin, Lesley D. L. Scott, Anthony P. F. Turner, Ferrocene-mediated enzyme electrode for amperometric determination of glucose. Analytical Chemistry. ,vol. 56, pp. 667- 671 ,(1984) , 10.1021/AC00268A018
Y. Degani, Adam. Heller, Direct electrical communication between chemically modified enzymes and metal electrodes. I. Electron transfer from glucose oxidase to metal electrodes via electron relays, bound covalently to the enzyme The Journal of Physical Chemistry. ,vol. 91, pp. 1285- 1289 ,(1987) , 10.1021/J100290A001