The chemical composition component of the distribution of chain length and long chain branching for copolymerization of olefins and polyolefin chains containing terminal double-bonds
作者： João B. P. Soares , Archie E. Hamielec
DOI: 10.1002/MATS.1997.040060301
关键词: Polyolefin 、 Macromonomer 、 Polymer 、 Molar mass distribution 、 Computational chemistry 、 Branching (polymer chemistry) 、 Chemistry 、 Double bond 、 Polymer chemistry 、 Copolymer 、 Molecule 、 Inorganic chemistry 、 Organic chemistry 、 Materials Chemistry 、 Polymers and Plastics 、 Condensed matter physics
摘要: An analytical solution for the distribution of molecular weight, long chain branching and chemical composition polyolefins produced under steady-state conditions with mechanism terminal is derived. The model predictions agree well Monte-Carlo simulation results. This detailed description microstructure polymer populations different levels can be useful in establishing structure-property relations these polymers.
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