Method of preparing furfural compounds

作者: Hyeon Su Heo , Kyung Hae Lee , Jong Min Lee , Moo Ho Lee

DOI:

关键词: Chemical formulaOrganic chemistrySolventAlkylationFurfuralAlcoholIsomerizationSubstrate (chemistry)ChemistryCatalysis

摘要: Provided is a two-step method of producing compound chemical formula 1 in the presence an alcohol solvent and Group 3B metal catalyst or salt thereof, comprising first step alkylation isomerization aldohexose-containing substrate to obtain intermediate, second dehydration intermediate produce 1. Preferably, additional and/or are not added step.

参考文章(14)
Gerardus Johannes Maria Gruter, 5-substituted 2-(alkoxymethyl)furans ,(2008)
Gerardus Johannes Maria Gruter, Frits Dautzenberg, Method for the synthesis of 5-alkoxymethyl furfural ethers and their use ,(2007)
Ana Sofia Vagueiro De Sousa Dias, Gerardus Johannes Maria Gruter, Robbert-Jan Van Putten, Process for the conversion of a carbohydrate-containing feedstock ,(2011)
Yuriy Román-Leshkov, Juben N Chheda, James A Dumesic, Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose Science. ,vol. 312, pp. 1933- 1937 ,(2006) , 10.1126/SCIENCE.1126337
Avelino Corma, Sara Iborra, Alexandra Velty, Chemical Routes for the Transformation of Biomass into Chemicals Chemical Reviews. ,vol. 107, pp. 2411- 2502 ,(2007) , 10.1021/CR050989D
Stanisław K. Tyrlik, Dorota Szerszeń, Marian Olejnik, Witold Danikiewicz, Selective dehydration of glucose to hydroxymethylfurfural and a one-pot synthesis of a 4-acetylbutyrolactone from glucose and trioxane in solutions of aluminium salts Carbohydrate Research. ,vol. 315, pp. 268- 272 ,(1999) , 10.1016/S0008-6215(99)00037-3
Yu Yang, Changwei Hu, Mahdi M. Abu-Omar, Conversion of glucose into furans in the presence of AlCl3 in an ethanol-water solvent system. Bioresource Technology. ,vol. 116, pp. 190- 194 ,(2012) , 10.1016/J.BIORTECH.2012.03.126
Ronald Thaddeus Raines, Joseph Bartholomew Binder, Chemical transformation of lignocellulosic biomass into fuels and chemicals ,(2009)