Chapter 6 – Nitrogen-Containing Molecular Systems at High Pressures and Temperature

摘要: This chapter briefly surveys current experimental capabilities for subjecting molecules to extreme conditions of pressure and temperature the use Raman infrared spectroscopy X-ray diffraction characterize solid-state chemistry some simple nitrogen molecular systems. The considers chiefly phase transformations vibration dynamics bearing systems, including polynitrogen species at high pressure. There has been considerable progress in study framework nitrides pressures. Our discussion on nitrogen-bearing systems complements other recent reviews exemplifying how even can be endowed P–T with unorthodox properties incarnations. Systematic explorations chemical domains made accessible by DAC techniques are still their infancy. Most experiments that shown table I was done during past five years. scope situ much enhanced availability advanced synchrotron radiation sources. value symbiotic interactions between theory experiment well exemplified case polynitrogen. References further resources provided.