The first ferric carboxylate with a three-dimensional hydrid open-framework (MIL-82): its synthesis, structure, magnetic behavior and study of its dehydration by Mössbauer spectroscopy
作者： Morgane Sanselme , Jean-Marc Grenèche , Myriam Riou-Cavellec , Gérard Férey , None
DOI: 10.1016/J.SOLIDSTATESCIENCES.2004.04.001
关键词: Crystallography 、 Transition metal 、 Chemistry 、 Antiferromagnetism 、 Mössbauer spectroscopy 、 Inorganic chemistry 、 Magnetism 、 Magnetic structure 、 Octahedron 、 Metamagnetism 、 Carboxylate
摘要: Abstract The new compound FeIII(OH)[C6H2(CO2)2(CO2H)2]·xH2O (with x=0.88) is the first ferric carboxylate with a 3D open structure that has been synthesized up to now. Its built from chains of octahedra connected by ligands; it displays small channels filled water molecules. removal molecules was studied Mossbauer spectroscopy which set defaults in crystal. Magnetic measurements indicate an antiferromagnetic behavior at low temperature, but also metamagnetic transition for applied magnetic field larger than 0.5 T.
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