Darstellung und strukturelle Charakterisierung von Thiocyanato‐Kupfer(II)‐Komplexen mit Liganden des Imidazol‐Typs
作者： A. Ma?lejov� , J. Kohout
关键词: Chemistry 、 Crystallography 、 Orbital # reduction 、 Spectral data 、 Ligand 、 Imidazole ligand
摘要: Dargestellt wurden Komplexverbindungen des Typs Cu(NCS)2L2, wobei L Imidazol, 1- evtl. 2-Methylimidazol, 1,2-Dimethylimidazol, Benzimidazol, 2-Methyl- und 2-athylbenzimidazol bedeutet. Auf Grund der ermittelten spektralen Daten wird diesen Komplexen tetragonale Stereochemie mit verschiedenem Grad axialen Wechselwirkung, in Abhangigkeit von den anwesenden L-Liganden, zugesprochen. Durch Auswertung orbitalen Reduktionsfaktoren werden die Bindungsverhaltnisse gegebenen Systemen kurz besprochen. Preparation and Structural Characterization of Thiocyanato Copper(II) Complexes with Imidazole Ligands Complexes the type Cu(NCS)2L2 were prepared (for see „Inhaltsubersicht”). Based on spectral data a tetragonal stereochemistry varying degree axial interaction was assigned to these complexes, dependence ligand. On basis evaluated orbital reduction factors, bondings given systems are briefly discussed.
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