Synthesis and characterization of ferrocenyl and bis(ferrocenyl) alkynes and polyynes: crystal structure of 1,4-bis(ferrocenyl)butadiyne and third order nonlinear optical properties of 1,8-bis(ferrocenyl)octatetrayne
作者： Zheng Yuan , Graham Stringer , Ian R. Jobe , David Kreller , Kimberly Scott
DOI: 10.1016/0022-328X(93)83181-T
关键词: Stereochemistry 、 Chemical coupling 、 Crystal structure 、 Coupling reaction 、 Metallocene 、 Crystallography 、 Chemistry 、 Third order nonlinear 、 Hyperpolarizability 、 Catalysis 、 Carbon-13 NMR
摘要: A simple method, utilizing a coupling reaction between ethynylferrocene and cis-1,2-dichloroethylene catalysed by Pd(PPh3)4/CuI or Pd(PPh3)2Cl2/CuI, for the stepwise preparation of ferrocenylbutadiyne is described. Complete 1H 13C NMR characterization (η-C5H5)Fe(η-C5H4)(CC)nH (n = 1, 2), (η-C5H5)Fe(η-C5H4)(CC)n(η-C5H4)Fe(η-C5H5) 2, 4) Z-(η-C5H5) Fe(η-C5H4)CCCHCHCl, an X-ray crystal structure study 1,4-bis(ferrocenyl)butadiyne, third order nonlinear optical behavior (second molecular hyperpolarizability, γ) 1,8-bis(ferrocenyl) octatetrayne are reported.
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