Understanding the complexation of Eu3+ with three diglycolamide-functionalized calix[4]arenes: spectroscopic and DFT studies
作者： Seraj Ahmad Ansari , Prasanta Kumar Mohapatra , Sheikh Musharaf Ali , Arijit Sengupta , Arunasis Bhattacharyya
DOI: 10.1039/C6DT00180G
关键词: Spectroscopy 、 Chemistry 、 Inorganic chemistry 、 Computational chemistry 、 Acetonitrile 、 Luminescence
摘要: Complexation of Eu3+ with three diglycolamide-functionalized calix[4]arene (C4DGA) ligands was investigated by UV-Vis and luminescence spectroscopy measurements in acetonitrile medium. The complexation thermodynamics studied micro-calorimetry while structural information obtained from DFT calculations.
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