The proton magnetic resonance spectra of conjugated aromatic hydrocarbons

作者:

DOI: 10.1098/RSPA.1956.0152

关键词: PyrenePhotochemistryAromaticityHydrocarbonAnthraceneAzuleneConjugated systemPhenanthreneBenzeneChemistry

摘要: The proton resonance spectra of a number alternant aromatic hydrocarbons are reported. With the exception benzene and pyrene, two or more signals were obtained for each hydrocarbon. A probable assignment spectrum compound is given, this was confirmed anthracene phenanthrene by deuteration. non-alternant hydrocarbon azulene also presented. observed nuclear magnetic cannot be interpreted on basis symmetry considerations $\pi $-electron density, but readily explained in terms simple model based induced diamagnetic currents conjugated rings. calculated satisfactorily reproduce main features spectra.

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