Elucidation of inorganic reaction mechanisms through volume profile analysis
作者： Grazyna Stochel , Rudi van Eldik
DOI: 10.1016/S0010-8545(99)00009-0
关键词: Small molecule 、 Chemistry 、 Reaction mechanism 、 Volume (thermodynamics) 、 Computational chemistry 、 Organic chemistry 、 High pressure 、 Bioinorganic chemistry 、 Ligand 、 Profile analysis 、 Chemical reaction
摘要: Abstract The application of high pressure kinetic and thermodynamic techniques in mechanistic studies chemical reactions solution, can contribute towards the elucidation underlying reaction mechanisms. In this review fundamental principles involved construction volume profiles interpretation latter are presented for various types inorganic, organometallic bioinorganic systems. These include thermal photo-induced ligand substitution electron-transfer reactions, as well processes that involve activation small molecules. insight gained through profile analysis non-symmetrical forms theme contribution.
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