Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds
作者： Yury V Tomilov , V A Dokitchev , Usein M Dzhemilev , Oleg M Nefedov
DOI: 10.1070/RC1993V062N09ABEH000048
关键词: Chemical synthesis 、 Chemistry 、 Catalytic decomposition 、 Cyclopropane 、 Metal 、 Organic chemistry 、 General method 、 Catalysis 、 Diazomethane
摘要: The principal advances and trends in the application of diazomethane as a methylenating agent synthetic chemistry using transition non-transition metal compounds catalysts are surveyed analysed. catalytic reactions with olefins, acethylenes, aromatic compounds, ketones, alcohols amines examined. A systematic account is given data concerning influence structure initial substrates nature catalyst components on regio- stereo-selectivity considered. possibilities conversion by (generated situ) unsaturated into cyclopropane derivatives bibliography includes 284 references.
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