Understanding the Anchoring Effect of Two-Dimensional Layered Materials for Lithium–Sulfur Batteries
作者： Qianfan Zhang , Yapeng Wang , Zhi Wei Seh , Zhongheng Fu , Ruifeng Zhang
DOI: 10.1021/ACS.NANOLETT.5B00367
关键词: Polysulfide 、 Lithium–sulfur battery 、 Materials science 、 Adsorption 、 Dissolution 、 Electrolyte 、 Lithium 、 Nanotechnology 、 Anchoring 、 van der Waals force
摘要: Although the rechargeable lithium–sulfur battery system has attracted significant attention due to its high theoretical specific energy, its implementation has been impeded by multiple challenges, especially the dissolution of intermediate lithium polysulfide (Li2S n) species into the electrolyte. Introducing anchoring materials, which can induce strong binding interaction with Li2S n species, has been demonstrated as an effective way to overcome this problem and achieve long-term cycling stability and high-rate performance. The interaction …
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sci-hub.se 参考文章(47)
Progress in Intercalation Research Kluwer Academic Publishers. ,(1994) , 10.1007/978-94-011-0890-4
Joongpyo Shim, Kathryn A. Striebel, Elton J. Cairns, The Lithium/Sulfur Rechargeable Cell Effects of Electrode Composition and Solvent on Cell Performance Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1503076
G. Kresse, J. Hafner, Ab initio molecular dynamics for open-shell transition metals. Physical Review B. ,vol. 48, pp. 13115- 13118 ,(1993) , 10.1103/PHYSREVB.48.13115
P. E. Blöchl, Projector augmented-wave method Physical Review B. ,vol. 50, pp. 17953- 17979 ,(1994) , 10.1103/PHYSREVB.50.17953
Rezan Demir-Cakan, Mathieu Morcrette, Farid Nouar, Carine Davoisne, Thomas Devic, Danielle Gonbeau, Robert Dominko, Christian Serre, Gérard Férey, Jean-Marie Tarascon, None, Cathode Composites for Li–S Batteries via the Use of Oxygenated Porous Architectures Journal of the American Chemical Society. ,vol. 133, pp. 16154- 16160 ,(2011) , 10.1021/JA2062659
Min-Sang Song, Sang-Cheol Han, Hyun-Seok Kim, Jin-Ho Kim, Ki-Tae Kim, Yong-Mook Kang, Hyo-Jun Ahn, SX Dou, Jai-Young Lee, None, Effects of Nanosized Adsorbing Material on Electrochemical Properties of Sulfur Cathodes for Li/S Secondary Batteries Journal of The Electrochemical Society. ,vol. 151, ,(2004) , 10.1149/1.1710895
John P. Perdew, Kieron Burke, Matthias Ernzerhof, Generalized Gradient Approximation Made Simple Physical Review Letters. ,vol. 77, pp. 3865- 3868 ,(1996) , 10.1103/PHYSREVLETT.77.3865
Yuan Yang, Guangyuan Zheng, Yi Cui, None, Nanostructured sulfur cathodes Chemical Society Reviews. ,vol. 42, pp. 3018- 3032 ,(2013) , 10.1039/C2CS35256G
Joo‐Seong Kim, Tae Hoon Hwang, Byung Gon Kim, Jaeyun Min, Jang Wook Choi, None, A Lithium‐Sulfur Battery with a High Areal Energy Density Advanced Functional Materials. ,vol. 24, pp. 5359- 5367 ,(2014) , 10.1002/ADFM.201400935
Guangyuan Zheng, Yuan Yang, Judy J Cha, Seung Sae Hong, Yi Cui, None, Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries Nano Letters. ,vol. 11, pp. 4462- 4467 ,(2011) , 10.1021/NL2027684