The regiochemical course of [2+2] cycloadditions of dichloroketene with vinyl- and alkynylsilanes
作者： Rick L. Danheiser , Howard Sard
DOI: 10.1016/S0040-4039(00)81316-7
关键词: Computational chemistry 、 Yield (chemistry) 、 Organic chemistry 、 Regioselectivity 、 Chemistry 、 Molecular orbital
摘要: Abstract Alkynylsilanes undergo regioselective [2+2] cycloadditions with dichloroketene in good yield; the regiochemical course of these reactions is accord frontier molecular orbital predictions.
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